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Preheat oven to 375 degrees F (190 degrees C). Position rack in centre of oven. Butter or line with paper 12 - 2 3/4 x 1 1/2 inch muffin cups.
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In a large measuring cup or bowl whisk together the melted butter, eggs, buttermilk, and vanilla extract.
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In another large bowl whisk together the flour, cocoa powder, sugar, baking powder, baking soda, and salt.
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With a rubber spatula fold the wet ingredients into the dry ingredients and stir only until the ingredients are combined. Do not over mix the batter or tough muffins will result.
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Evenly fill the muffin cups with the batter (the muffin cups will be full), using two spoons or an ice cream scoop. Place in the oven and bake until a toothpick inserted in the centre of a muffin comes out clean, about 20 minutes. Transfer to a wire rack and let cool for about 5 minutes before removing from pan.